AIBN-Initiated Radical Reactions of Ethyl Phosphinate

Monika I. Antczak, Jean-Luc Montchamp*

*Department of Chemistry , Texas Christian University, Box 298860, Fort Worth, TX 76129, USA, Email: j.montchamptcu.edu

M. I. Antczak, J.-L. Montchamp, Synthesis, 2006, 3080-3084.

DOI: 10.1055/s-2006-950203

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Abstract

Ethyl phosphinate adds to alkenes and alkynes under thermal radical conditions with AIBN as the initiator to give H-phosphinates in good yields.

see article for more examples

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Palladium-Catalyzed Hydrophosphinylation of Alkenes and Alkynes

S. Deprele, J.-L. Montchamp, J. Am. Chem. Soc., 2002, 124, 9386-9387.

Triethylborane-Initiated Room Temperature Radical Addition of Hypophosphites to Olefins:  Synthesis of Monosubstituted Phosphinic Acids and Esters

S. Deprèle, J.-L. Montchamp, J. Org. Chem., 2001, 66, 6745-6755.

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Key Words

phosphorus, free radical, phosphinates, AIBN, hypophosphite

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ID: J66-Y2006-2940