Efficient and Selective Al-Catalyzed Alcohol Oxidation via Oppenauer Chemistry
Christopher R. Graves, Bi-Shun Zeng, and SonBinh T. Nguyen*
*Department of Chemistry and Institute for Environmental Catalysis, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, Email: stnnorthwestern.edu
C. R. Graves, B.-S. Zeng, S. T. Nguyen, J. Am. Chem. Soc., 2006, 128, 12596-12597.
DOI: 10.1021/ja063842s
Abstract
A highly active and selective Al-based catalytic Oppenauer oxidation allows quantitative and selective oxidations of a variety of benzylic, propargylic, allylic, and aliphatic primary and secondary alcohols using nitrobenzaldehyde derivatives as the oxidant and simple aluminum compounds as precatalysts.
see article for more examples
see article for more reactions
Key Words
Oppenauer Oxidation, Ketones, Aldehydes
ID: J48-Y2006-3140