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Straightforward and Highly Efficient Catalyst-Free One-Pot Synthesis of Dithiocarbamates under Solvent-Free Conditions

Najmedin Azizi, Fezzeh Aryanasab and Mohammad R. Saidi*

*Department of Chemistry, Sharif University of Technology, P. O. Box 11465-9516, Tehran 11365, Email: saidisharif.edu

N. Azizi, F. Aryanasab, M. R. Saidi, Org. Lett., 2006, 8, 5275-5277.

DOI: 10.1021/ol0620141 (free Supporting Information)


Abstract

A highly efficient, mild and simple synthesis of dithiocarbamates is based on the one-pot reaction of amines, CS2, and alkyl halides without using a catalyst under solvent-free conditions. The reaction is a highly atom-economic process for production of S-alkyl thiocarbamates.


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Waste-Free and Environment-Friendly Uncatalyzed Synthesis of Dithiocarbamates under Solvent-Free Conditions

N. Azizi, F. Ebrahimi, E. Aakbari, F. Aryanasab, M. R. Saidi, Synlett, 2007, 2797-2800.


Key Words

Dithiocarbamates, Amination, Green Chemistry, Multicomponent Reactions


ID: J54-Y2006-3610