Isomerization-Free Allylic Alkylations of Terminal π-Allyl Palladium Complexes
Katja Krämer and Uli Kazmaier*
*Institut für Organische Chemie, Universität des Saarlandes, D-66123
Saarbrücken, E-mail: u.kazmaier
mx.uni-saarland.de
K. Krämer, U. Kazmaier, J. Org. Chem., 2006, 71, 8950-8953.
DOI: 10.1021/jo061362d
Abstract
Chelated amino acid ester enolates are excellent nucleophiles for allylic alkylations. With these enolates, even terminal π-allyl palladium complexes react without significant isomerization.
see article for more examples
Aromatic Nitro Groups and Their Reactions with Chelated Ester Enolates
D. Stolz, U. Kazmaier, R. Pick, Synthesis, 2006, 3341-3347.
Key Words
amino acids, allylation, esters, Tsuji-Trost Reaction
ID: J42-Y2006-3690
