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RuCl3-Catalyzed Oxidation of Iodoarenes with Peracetic Acid: New Facile Preparation of Iodylarenes

Alexey Y. Koposov, Rashad R. Karimov, Andrey A. Pronin, Tatyana Skrupskaya, Mekhman S. Yusubov and Viktor V. Zhdankin*

*Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota, 55812, Email: vzhdankid.umn.edu

A. Y. Koposov, R. R. Karimov, A. A. Pronin, T. Skrupskaya, M. S. Yusubov, V. V. Zhdankin, J. Org. Chem., 2006, 71, 9912-9914.

DOI: 10.1021/jo062073s


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Abstract

A facile ruthenium-catalyzed methodology for the preparation of pentavalent iodine compounds uses peracetic acid as an oxidant. The new procedure allows the preparation of iodylarenes bearing strongly electron-withdrawing groups.

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2-Iodylphenol Ethers: Preparation, X-ray Crystal Structure, and Reactivity of New Hypervalent Iodine(V) Oxidizing Reagents

A. Y. Koposov, R. R. Karimov, I. M. Geraskin, V. N. Nemykin, V. V. Zhdankin, J. Org. Chem., 2006, 71, 8452-8458.


Key Words

Hypervalent Iodine Compounds, Peracetic Acid, Ruthenium


ID: J42-Y2006-4150