RuCl3-Catalyzed Oxidation of Iodoarenes with Peracetic Acid: New Facile Preparation of Iodylarenes
Alexey Y. Koposov, Rashad R. Karimov, Andrey A. Pronin, Tatyana Skrupskaya, Mekhman S. Yusubov and Viktor V. Zhdankin*
*Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota, 55812, Email: vzhdankid.umn.edu
A. Y. Koposov, R. R. Karimov, A. A. Pronin, T. Skrupskaya, M. S. Yusubov, V. V. Zhdankin, J. Org. Chem., 2006, 71, 9912-9914.
DOI: 10.1021/jo062073s
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Abstract
A facile ruthenium-catalyzed methodology for the preparation of pentavalent iodine compounds uses peracetic acid as an oxidant. The new procedure allows the preparation of iodylarenes bearing strongly electron-withdrawing groups.
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A. Y. Koposov, R. R. Karimov, I. M. Geraskin, V. N. Nemykin, V. V. Zhdankin, J. Org. Chem., 2006, 71, 8452-8458.
Key Words
Hypervalent Iodine Compounds, Peracetic Acid, Ruthenium
ID: J42-Y2006-4150