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Pd/P(t-Bu)3: A Mild Catalyst for Selective Reduction of Alkenes under Transfer-Hydrogenation Conditions

Jean Michel Brunel*

*Laboratoire Synthèse et Etude de Substances Naturelles à Activités Biologiques (SESNAB), Faculté des Sciences et Techniques de St Jérôme, Case 342, Université Paul Cézanne, Aix-Marseille III, Avenue Escadrille Normandie Niémen, 13397 Marseille cedex 20, France, Email: bruneljmyahoo.fr

J. M. Brunel, Synlett, 2007, 330-332.

DOI: 10.1055/s-2007-968005


Abstract

Pd/P(t-Bu)3 is an efficient and mild catalyst for selective reduction of various alkenes under transfer-hydrogenation conditions leading to the corresponding saturated derivatives in good yields.

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Key Words

palladium, reduction of alkenes, reduction of α,β-unsaturated compounds, tri-tert-butyl phosphine, transfer hydrogenation, formic acid, catalysis


ID: J60-Y2007-0880