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Synthesis of 1,3,5-Tricarbonyl Derivatives by Condensation of 1,3-Bis(silyl enol ethers) with Acid Chlorides

Thomas Rahn, Van T. H. Nguyen, T. H. Tam Dang, Zafar Ahmed, Karen Methling, Michael Lalk, Christine Fischer, Anke Spannenberg and Peter Langer*

*Institut für Chemie, Universität Rostock, Albert-Einstein-Strasse 3a, 18059 Rostock, Germany, Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Email: peter.langeruni-rostock.de

T. Rahn, V. T. H. Nguyen, T. H. T. Dang, Z. Ahmed, K. Methling, M. Lalk, C. Fischer, A. Spannenberg, P. Langer, J. Org. Chem., 2007, 72, 1957-1961.

DOI: 10.1021/jo062153w


Abstract

Various 1,3,5-tricarbonyl derivatives were prepared by a mild reaction of 1,3-bis(silyl enol ethers) with acid chlorides. Reactions of both aromatic and aliphatic acid chlorides and bis(acid chlorides) were conducted.

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Key Words

1,3-dicarbonyl compounds


ID: J42-Y2007-0890