Silylation of Aryl Iodides with 1,1,1,3,5,5,5-Heptamethyltrisiloxane Catalyzed by Transition-Metal Complexes

Miki Murata*, Kosuke Ota, Hiroyuki Yamasaki, Shinji Watanabe, Yuzuru Masuda

*Department of Materials Science, Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Email: muratamkmail.kitami-it.ac.jp

M. Murata, K. Ota, H. Yamasaki, S. Watanabe, Y. Masuda, Synlett, 2007, 1387-1390.

DOI: 10.1055/s-2007-980343

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Abstract

The silylation of various aryl iodides with 1,1,1,3,5,5,5-heptamethyltrisiloxane was achieved using transition-metal catalysts, such as Pd(0), Pt(0), and Rh(I), which offer a dramatically different substrate scope.

see article for more examples

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Rhodium(I)-Catalyzed Silylation of Aryl Halides with Triethoxysilane: Practical Synthetic Route to Aryltriethoxysilanes

M. Murata, M. Ishikura, M. Nagata, S. Watanabe, Y. Masuda, Org. Lett., 2002, 4, 1843-1845.

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Key Words

silicon, arylsiloxanes, transition metals, catalysis, cross-coupling, aryl halides

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ID: J60-Y2007-1790