Silylation of Aryl Iodides with 1,1,1,3,5,5,5-Heptamethyltrisiloxane Catalyzed by Transition-Metal Complexes
Miki Murata*, Kosuke Ota, Hiroyuki Yamasaki, Shinji Watanabe, Yuzuru Masuda
*Department of Materials Science, Kitami Institute of Technology, 165 Koencho, Kitami 090-8507, Japan, Email: muratamkmail.kitami-it.ac.jp
M. Murata, K. Ota, H. Yamasaki, S. Watanabe, Y. Masuda, Synlett, 2007, 1387-1390.
DOI: 10.1055/s-2007-980343
Abstract
The silylation of various aryl iodides with 1,1,1,3,5,5,5-heptamethyltrisiloxane was achieved using transition-metal catalysts, such as Pd(0), Pt(0), and Rh(I), which offer a dramatically different substrate scope.
see article for more examples
M. Murata, M. Ishikura, M. Nagata, S. Watanabe, Y. Masuda, Org. Lett., 2002, 4, 1843-1845.
Key Words
silicon, arylsiloxanes, transition metals, catalysis, cross-coupling, aryl halides
ID: J60-Y2007-1790