Diamination of Conjugated Dienes and Trienes Catalyzed by N-Heterocyclic Carbene-Pd(0) Complexes

Liang Xu, Haifeng Du and Yian Shi*

*Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, Email: yianlamar.colostate.edu

L. Xu, H. Du, Y. Shi, J. Org. Chem., 2007, 72, 7038-7041.

DOI: 10.1021/jo0709394

---

Abstract

The use of di-t-butyldiaziridinone as nitrogen source and a N-heterocyclic carbene-Pd(0) complex as catalyst allows an efficient diamination of a wide variety of conjugated dienes and trienes in good yields with high regio- and stereoselectivities.

see article for more examples

---

---

Catalytic Asymmetric Synthesis of Cyclic Sulfamides from Conjugated Dienes

R. G. Cornwall, B. Zhao, Y. Shi, Org. Lett., 2013, 15, 796-799.

Cu(I)-Catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways

B. Zhao, X. Peng, S. Cui, Y. Shi, J. Am. Chem. Soc., 2010, 132, 11009-11011.

A Pd(0)-Catalyzed Diamination of Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under Solvent-Free Conditions

H. Du, W. Yuan, B. Zhao, Y. Shi, J. Am. Chem. Soc., 2007, 129, 7496-7497.

---

Key Words

1,2-diamination, imidazolidones

---

ID: J42-Y2007-2850