Scandium Triflate Catalyzed Aminolysis of meso-Aziridines
Saravanan Peruncheralathan, Michael Henze, Christoph Schneider*
*Institut für Organische Chemie, Universität Leipzig,
Johannisallee 29, 04103 Leipzig, Germany, Email: schneider
chemie.uni-leipzig.de
S. Peruncheralathan, M. Henze, C. Schneider, Synlett, 2007, 2289-2291.
DOI: 10.1055/s-2007-984920
see article for more reactions
Abstract
The aminolysis of meso-N-phenyl aziridines is efficiently catalyzed by 1 mol% of Sc(OTf)3 and furnishes valuable 1,2-diamines in good to excellent yields.
see article for more examples
Iron-Catalyzed Ring-Opening of meso-Aziridines with Amines
A. Marti, L. Richter, C. Schneider, Synlett, 2011, 2513-2516.
Key Words
amines, aziridines, 1,2-diamines, catalysis, scandium
ID: J60-Y2007-3030
