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SmCl3-Catalyzed C-Acylation of 1,3-Dicarbonyl Compounds and Malononitrile

Quansheng Shen, Wen Huang, Jialiang Wang and Xigeng Zhou*

*Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, People's Republic of China, Email: xgzhoufudan.edu.cn

Q. Shen, W. Huang, J. Wang, X. Zhou, Org. Lett., 2007, 9, 4491-4494.

DOI: 10.1021/ol701961z


Abstract

A recyclable, convenient, and efficient catalytic system allows the C-acylation of 1,3-dicarbonyl compounds and malononitrile with acid chlorides in moderate to excellent yields under mild conditions.


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Key Words

Acylation, Active Methylenes


ID: J54-Y2007-3340