Aminochlorination in Water: First Brønsted Acid-Promoted Synthesis of Vicinal Chloramines
Xue-Liang Wu and Guan-Wu Wang*
*Department of Chemistry, University of Science and
Technology of China, Hefei, Anhui 230026, People's Republic of China,
Email: gwang
ustc.edu.cn
X.-L. Wu, G.-W. Wang, J. Org. Chem., 2007, 72, 9398-9401.
DOI: 10.1021/jo701957t
Abstract
A practical, regio- and diastereoselective synthesis of vicinal chloramines from electron-deficient olefins and Chloramine-T is promoted by Brønsted acids in water. This novel protocol is efficient, mild, ecofriendly, and broadly applicable for the aminochlorination of various electron-deficient olefins including α,β-unsaturated ketones, cinnamate, and cinnamide.
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Key Words
Aminochlorination, Green Chemistry, Chloramine-T
ID: J42-Y2007-3800
