Platinum-Catalyzed Regio- and Stereoselective Arylthiolation of Internal Alkynes
Fumikazu Yamashita, Hitoshi Kuniyasu,* Jun Terao and Nobuaki Kambe
*Department of Applied Chemistry, Graduate School of
Engineering, Osaka University, Suita, Osaka 565-0871, Japan, Email: kuni
chem.eng.osaka-u.ac.jp
F. Yamashita, H. Kuniyasu, J. Terao, N. Kambe, Org. Lett., 2008, 10, 101-104.
DOI: 10.1021/ol7025069
Abstract
Unsymmetrical internal alkynes such as ethyl phenylpropiolate successfully underwent Pt-catalyzed decarbonylative arylthiolation by thioesters.
see article for more examples
Key Words
ID: J54-Y2008-0040
