Beckmann Rearrangement of Ketoximes to Lactams by Triphosphazene Catalyst
Masaharu Hashimoto, Yasushi Obora, Satoshi Sakaguchi and Yasutaka Ishii*
*Department of Chemistry and Material Engineering, Faculty of
Chemistry, Materials and Bioengineering & High Technology Research Center,
Kansai University, Suita, Osaka 564-8680, Japan, Email: ishii
ipcku.kansai-u.ac.jp
M. Hashimoto, Y. Obora, S. Sakaguchi, Y. Ishii, J. Org. Chem., 2008, 73, 2894-2897.
DOI: 10.1021/jo702277g
Abstract
Triphosphazene (TAPC) was found to be an efficient catalyst for the Beckmann rearrangement of various ketoximes to lactams.
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Key Words
Beckmann Rearrangement, Organocatalysis
ID: J42-Y2008-0960
