Efficient Preparation of Terminal Conjugated Dienes by Coupling of Dienol Phosphates with Grignard Reagents under Iron Catalysis
Gérard Cahiez, Vanessa Habiak and Olivier Gager
*Laboratoire de Synthèse Organique Sélective et de Chimie
Organomtallique (SOSCO), UMR 8123 CNRS-UCP-ESCOM, 5, Mail Gay-Lussac, Neuville
sur Oise, F-95031 Cergy-Pontoise cedex, France, Email: gerard.cahiez
chim.u-cergy.fr
G. Cahiez, V. Habiak, O. Gager, Org. Lett., 2008, 10, 2389-2392.
DOI: 10.1021/ol800816f
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Abstract
An efficient new route by coupling Grignard reagents and dienol phosphates in the presence of Fe(acac)3 allows a stereoselective preparation of terminal conjugated dienes.
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Key Words
ID: J54-Y2008-1550
