Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Aryl Sulfides and Alkenyl Alkyl Sulfides with Alkyl Grignard Reagents Using (Z)-3,3-Dimethyl-1,2-bis(diphenylphosphino)but-1-ene as Ligand
Shigenari Kanemura, Azusa Kondoh, Hideki Yorimitsu*, Koichiro Oshima*
*Department of Material Chemistry, Graduate School of
Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto
615-8510, Japan, Email: yori
orgrxn.mbox.media.kyoto-u.ac.jp,
oshimaorgrxn.mbox.media.kyoto-u.ac.jp
S. Kanemura, A. Kondoh, H. Yorimitsu, K. Oshima, Synthesis, 2008, 2659-2660.
Abstract
A combination of nickel(II) acetylacetonate and (Z)-3,3-dimethyl-1,2-bis(diphenylphosphino)but-1-ene catalyzes cross-coupling reactions of alkyl aryl sulfides and alkenyl alkyl sulfides with primary and secondary alkyl Grignard reagents.
see article for more examples
Key Words
arenes, alkenes, cross-coupling, nickel, sulfur, ligands, magnesium
ID: J66-Y2008-2320
