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Palladium-Catalyzed Carbon−Sulfur Cross-Coupling Reactions with Indium Tri(organothiolate) and Its Application to Sequential One-Pot Processes

Jae-Young Lee and Phil Ho Lee*

*National Research Laboratory for Catalytic Organic Reaction, Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea, Email:

J.-Y. Lee, P. H. Lee, J. Org. Chem., 2008, 73, 7413-7416.

DOI: 10.1021/jo801169h

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Indium tri(organothiolate) derivatives are effective nucleophilic coupling partners in Pd-catalyzed C-S crosscoupling reactions to produce functionalized sulfides in excellent yields with high atom efficiency and complete regio- and chemoselectivity.

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Key Words

Aryl Sulfides, Vinyl Sulfides

ID: J42-Y2008-2590