2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone
Muhammet Uyanik, Matsujiro Akakura and Kazuaki Ishihara*
*Graduate School of Engineering, Nagoya University, Furo-cho,
Chikusa-ku, Nagoya 464-8603, Japan, Email: ishihara
cc.nagoya-u.ac.jp
M. Uyanik, M. Akakura, K. Ishihara, J. Am. Chem. Soc., 2009, 131, 251-262.
DOI: 10.1021/ja807110n
see article for more reactions
Abstract
2-Iodoxybenzenesulfonic acid, which can be generated in situ from 2-iodobenzenesulfonic acid sodium salt, is a much more active catalyst than modified IBXs for the oxidation of alcohols with Oxone. Highly efficient and selective methods for the oxidation of alcohols to carbonyl compounds such as aldehydes, carboxylic acids, and ketones were established.
see article for more examples
Key Words
Ketones, Aldehydes, Enones, Hypervalent Iodine Compounds, Oxone, Organocatalysis
ID: J48-Y2009-0100
