Zinc-Catalyzed Nucleophilic Substitution Reaction of Chlorosilanes with Organomagnesium Reagents
Kei Murakami, Hideki Yorimitsu* and Koichiro Oshima*
*Department of Material Chemistry, Graduate School of
Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto
615-8510, Japan, Email: yori
orgrxn.mbox.media.kyoto-u.ac.jp,
oshimaorgrxn.mbox.media.kyoto-u.ac.jp
K. Murakami, H. Yorimitsu, K. Oshima, J. Org. Chem., 2009, 74, 1415-1417.
DOI: 10.1021/jo802433t
Abstract
A zinc-catalyzed nucleophilic substitution reaction of chlorosilanes with organomagnesium reagents affords a broad range of functionalized tetraorganosilanes under mild reaction conditions. The reaction can be performed on large scale.
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Key Words
Alkylsilanes, Vinylsilanes, Arylsilanes, Allylsilanes
ID: J42-Y2009-0510
