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Acyl Transfer Catalysis with 1,2,4-Triazole Anion

Xing Yang and Vladimir B. Birman*

*Department of Chemistry, Washington University, Campus Box 1134, One Brookings Drive, St. Louis, Missouri 63130, Email: birmanwustl.edu

X. Yang, V. B. Birman, Org. Lett., 2009, 11, 1499-1502.

DOI: 10.1021/ol900098q (free Supporting Information)


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Abstract

Deprotonated 1,2,4-triazole is an active acyl transfer catalyst suitable for the aminolysis and transesterification of esters.


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proposed mechanism



Key Words

Acetamides, Amides, Organocatalysis


ID: J54-Y2009-0990