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Intermolecular Hydroamination between Nonactivated Alkenes and Aniline Catalyzed by Lanthanide Salts in Ionic Solvents

Peng Yin and Teck-Peng Loh*

*Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Email: teckpengntu.edu.sg

P. Yin, T.-P. Loh, Org. Lett., 2009, 11, 3791-3793.

DOI: 10.1021/ol9012074


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Abstract

An efficient intermolecular hydroamination of unactivated alkenes with anilines catalyzed by lanthanide salts gives Markovnikov products in good yields.

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Key Words

Arylamines, Ionic Liquids


ID: J54-Y2009-2570