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Pd-Catalyzed Synthesis of Allylic Silanes from Allylic Ethers

Ralph Moser, Takashi Nishikata and Bruce H. Lipshutz*

*Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, Email:

R. Moser, T. Nishikata, B. H. Lipshutz, Org. Lett., 2010, 12, 28-31.

DOI: 10.1021/ol9023908


Pd-catalyzed silylation of allylic phenyl ethers as electrophiles with organodisilanes can be run at room temperature in water as the only medium using micellar catalysis.

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ID: J54-Y2010-0030