Impregnated Copper on Magnetite as Recyclable Catalyst for the Addition of Alkoxy Diboron Reagents to C-C Double Bonds
Rafael Cano, Diego J. Ramón* and Miguel Yus*
*Instituto de Síntesis Orgánica (ISO) and Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Alicante, Apdo. 99, E-03080-Alicante, Spain, Email: djramonua.es, yusua.es
R. Cano, D. J. Ramón, M. Yus, J. Org. Chem., 2010, 75, 3458-3460.
DOI: 10.1021/jo100325e
Abstract
A simple protocol for the borylation of alkenes with use of impregnated copper on magnetite showed a very broad scope. All type of olefins could be used with similar results. The catalyst can be magnetically removed and reused several times, showing similar activity.
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ID: J42-Y2010-1270