Palladium Nanoparticle Catalyzed Hiyama Coupling Reaction of Benzyl Halides
Dipankar Srimani, Ansuman Bej and Amitabha Sarkar*
*Department of Organic Chemistry, Indian Association for the
Cultivation of Science, Kolkata 700032, Email: ocas
iacs.res.in
D. Srimani, A. Bej, A. Sarkar, J. Org. Chem., 2010, 75, 4296-4299.
DOI: 10.1021/jo1003373
Abstract
An efficient Hiyama coupling reaction between benzylic halides and aryltrialkoxysilanes using Pd nanoparticles allows the synthesis of a diverse range of diarylmethanes which are ubiquitous units of natural products and pharmaceuticals.
see article for more examples
Convenient Synthesis of Palladium Nanoparticles and Catalysis of Hiyama Coupling Reaction in Water
D. Srimani, S. Sawoo, A. Sarkar, Org. Lett., 2007, 9, 3639-3642.
Key Words
Hiyama Coupling, Benzylation, Allylation
ID: J42-Y2010-1700
