Asymmetric CuH-Catalyzed 1,4-Reductions in Water at Room Temperature
Shenlin Huang, Karl R. Voigtritter, John B. Unger, Bruce H. Lipshutz*
*Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA, Email: lipshutzchem.ucsb.edu
S. Huang, K. R. Voigtritter, H. B. Unger, B. H. Lipshutz, Synlett, 2010, 2041-2044.
see article for more reactions
Taking advantage of micellar catalysis in water, asymmetric hydrosilylation reactions can be conducted at ambient temperatures using water as the global medium.
see article for more examples
Asymmetric 1,4-Hydrosilylations of α,β-Unsaturated Esters
B. H. Lipshutz, J. M. Servesko, B. R. Taft, J. Am. Chem. Soc., 2004, 126, 8352-8353.
copper hydride, PMHS, hydrosilylations, reduction, asymmetric catalysis, micellar catalysis, green chemistry