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Rapid Nickel-Catalyzed Suzuki-Miyaura Cross-Couplings of Aryl Carbamates and Sulfamates Utilizing Microwave Heating

Mostafa Baghbanzadeh, Christian Pilger and C. Oliver Kappe*

*Christian Doppler Laboratory for Microwave Chemistry (CDLMC) and Institute of Chemistry, Karl-Franzens-University, Graz, Heinrichstrasse 28, 8010 Graz, Austria, Email: oliver.kappeuni-graz.at

M. Baghbanzadeh, C. Pilger, C. O. Kappe, J. Org. Chem., 2011, 76, 1507-1510.

DOI: 10.1021/jo1024464 (free Supporting Information)


Abstract

High-speed and scalable nickel-catalyzed cross-coupling of arylboronic acids with aryl carbamates and sulfamates is achieved by using sealed-vessel microwave processing.

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Key Words

Biaryls, Suzuki Coupling, Microwave Synthesis


ID: J42-Y2011-0580