Pd-Catalyzed C-H Activation/C-N Bond Formation: A New Route to 1-Aryl-1H-benzotriazoles
Rapolu Kiran Kumar, Md Ashif Ali and Tharmalingam Punniyamurthy*
*Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati-781039, India, Email: tpunniiitg.ernet.in
R. K. Kumar, M. A. Ali, T. Punniyamurthy, Org. Lett., 2011, 13, 2102-2105.
DOI: 10.1021/ol200523a
Abstract
C-H activation of aryl triazene compounds followed by intramolecular amination in the presence of a catalytic amount of Pd(OAc)2 provides 1-aryl-1H-benzotriazoles at moderate temperature.
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ID: J54-Y2011-1140