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Palladium-Catalyzed Carbon-Monoxide-Free Aminocarbonylation of Aryl Halides Using N-Substituted Formamides as an Amide Source

Dinesh N. Sawant, Yogesh S. Wagh, Kushal D. Bhatte and Bhalchandra M. Bhanage*

*Department of Chemistry, Institute of Chemical Technology, N. Parekh Marg, Matunga, Mumbai-400019, India, Email: bm.bhanageictmumbai.edu.in

D. N. Sawant, Y. S. Wagh, K. D. Bhatte, B. M. Bhanage, J. Org. Chem., 2011, 76, 5489-5494.

DOI: 10.1021/jo200754v (free Supporting Information)


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Abstract

A carbon-monoxide-free aminocarbonylation of various N-substituted formamides with aryl iodides and aryl bromides using palladium acetate and Xantphos is applicable for a wide range of formamides and aryl halides containing different functional groups furnishing good to excellent yield of the corresponding products.


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Key Words

benzamides


ID: J42-Y2011-1920