Iron-Catalyzed Ring-Opening of meso-Aziridines with Amines
Alex Marti, Luise Richter, Christoph Schneider*
*Institut für Organische Chemie, Universität Leipzig,
Johannisallee 29, 04103 Leipzig, Germany, Email: schneiderchemie.uni-leipzig.de
A. Marti, L. Richter, C. Schneider, Synlett, 2011, 2513-2516.
DOI: 10.1055/s-0030-1260338
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Abstract
A cationic iron complex catalyzes the aminolysis of meso-N-aryl aziridines very efficiently and furnishes valuable 1,2-diamines in excellent yields. This protocol is compatible with a range of functional groups both in the aziridine and amine components.
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Scandium Triflate Catalyzed Aminolysis of meso-Aziridines
S. Peruncheralathan, M. Henze, C. Schneider, Synlett, 2007, 2289-2291.
Key Words
amines, aziridines, 1,2-diamines, catalysis, iron
ID: J60-Y2011-2960