Aryne Insertion into I-I σ-Bonds
Diego Rodríguez-Lojo, Agustín Cobas, Diego Peña, Dolores Pérez* and Enrique Guitián*
*Centro de Investigación en Química Biolóxica e Materiais
Moleculares (CIQUS), and Departamento de Química Orgánica, Universidade de
Santiago, 15782 Santiago de Compostela, Spain, Email: enrique.guitian
usc.es,
dolores.perezusc.es
D. Rodríguez-Lojo, A. Cobas, D. Peña, D. Pérez, E. Guitián, Org. Lett., 2012, 14, 1363-1365.
DOI: 10.1021/ol300439r
Abstract
An efficient diiodination process, that involves the formal insertion of arynes into the I-I σ-bond, allows the synthesis of substituted and polycyclic o-diiodoarenes, which are difficult to obtain by classical methods.
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Key Words
ID: J54-Y2012-0730
