Stereoselective Alkene Isomerization over One Position
Casey R. Larsen and Douglas B. Grotjahn*
*Department of Chemistry and Biochemistry, San Diego State University, San Diego, California 92182-1030, United States, Email: grotjahnsciences.sdsu.edu
C. R. Larsen, D. B. Grotjahn, J. Am. Chem. Soc., 2012, 134, 10357-10360.
DOI: 10.1021/ja3036477
see article for more reactions
Abstract
A ruthenium complex is a very efficient catalyst for selective mono-isomerization of various multifunctional alkenes to afford E-products. Many reactions are complete within 10 min at room temperature. Even sensitive enols and enamides susceptible to further reaction can be generated. Very low catalyst loadings can be employed.
see article for more examples
Key Words
ID: J48-Y2012-1980