Simple and Practical Method for Preparation of [(Diacetoxy)iodo]arenes with Iodoarenes and m-Chloroperoxybenzoic Acid
Masataka Iinuma, Katsuhiko Moriyama, Hideo Togo*
*Graduate School of Science, Chiba University, Yayoi-cho 1-33, Inage-ku, Chiba 263-8522, Japan, Email: togofaculty.chiba-u.jp
M. Iinuma, K. Moriyama, H. Togo, Synlett, 2012, 23, 2663-2666.
Various [(diacetoxy)iodo]arenes were efficiently prepared by the treatment of iodoarenes with m-chloroperoxybenzoic acid in acetic acid. The great advantage of the present method is the easy preparation and isolation of [(diacetoxy)-iodo]arenes bearing electron-withdrawing groups.
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[(diacetoxy)iodo]arene, m-chloroperoxybenzoic acid, iodoarene, oxidation, acetic acid, electron-deficient aromatic ring