A Practical Protocol for the Hiyama Cross-Coupling Reaction Catalyzed by Palladium on Carbon
Yasunari Monguchi*, Takayoshi Yanase, Shigeki Mori, Hironao Sajiki*
*Laboratory of Organic Chemistry, Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan, Email: monguchigifu-pu.ac.jp, sajikigifu-pu.ac.jp
Y. Monguchi, T. Yanase, S. Mori, H. Sajiki, Synthesis, 2013, 45, 40-44.
DOI: 10.1055/s-0032-1316801 (free Supporting Information)
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A palladium on carbon (Pd/C) catalyzed cross-coupling reaction between aryl halides and trialkoxy(aryl)silanes enables the preparation of a range of biaryl compounds in the presence of a small amount of water and tris(4-fluorophenyl)phosphine as a ligand.
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