Sterically Controlled Iodination of Arenes via Iridium-Catalyzed C-H Borylation
Benjamin M. Partridge and John F. Hartwig*
*Department of Chemistry, University of California, Berkeley, California 94720, United States, Email: jhartwigberkeley.edu
B. M. Partridge, J. F. Hartwig, Org. Lett., 2013, 15, 140-143.
DOI: 10.1021/ol303164h
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Abstract
The regioselectivity of a mild method to prepare aryl and heteroaryl iodides by sequential C-H borylation and iodination is controlled by steric effects on the C-H borylation step and is complementary to existing methods to form aryl iodides.
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Key Words
ID: J54-Y2013-0060