Ni-Catalyzed Direct Carboxylation of Benzyl Halides with CO2
Thierry Leˇn, Arkaitz Correa and Ruben Martin*
*Institute of Chemical Research of Catalonia (ICIQ), Av. Pa´sos Catalans 16, 43007 Tarragona, Spain, Email: rmartinromoiciq.es
T. Leˇn, A. Correa, R. Martin, J. Am. Chem. Soc., 2013, 135, 1221-1224.
DOI: 10.1021/ja311045f (free Supporting Information)
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A Ni-catalyzed carboxylation of benzyl halides with CO2 proceeds under mild conditions at room temperature under atmospheric pressure. The method does not require well-defined and sensitive organometallic reagents and thus is user-friendly and operationally simple.
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M. B÷rjesson, T. Moragas, R. Martin, J. Am. Chem. Soc., 2016, 138, 7504-7507.
Y. Liu, J. Cornella, R. Martin, J. Am. Chem. Soc., 2014, 136, 11212-11215.