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Palladium-Catalyzed Hiyama-Type Cross-Coupling Reactions of Arenesulfinates with Organosilanes

Kai Cheng, Sai Hu, Baoli Zhao, Xian-Man Zhang and Chenze Qi*

*Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000, People's Republic of China, Email:

K. Cheng, S. Hu, B. Zhao, X.-M. Zhang, C. Qi, J. Org. Chem., 2013, 78, 5022-5025.

DOI: 10.1021/jo302791q


Palladium-catalyzed Hiyama-type cross-coupling reactions of various arenesulfinates with organosilanes were achieved in high yields under aerobic conditions at 70C in the presence of tetrabutylammonium fluoride. These cross-coupling reactions show wide functional group tolerance.

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Key Words

Hiyama Coupling, Biaryls

ID: J42-Y2013