Micro and Nanobubble Based Strategy for Gas-Liquid-Solid Multiphase Reactions: Palladium-Catalysed Hydrogenation of Carbon-Carbon Unsaturated Bonds
Nobuyuki Mase*, Shogo Isomura, Mitsuo Toda, Naoharu Watanabe
*Department of Applied Chemistry and Biochemical Engineering,
Graduate School of Engineering, Shizuoka University, 3-5-1 Johoku, Hamamatsu,
Shizuoka 432-8561, Japan,
Email: tnmase
ipc.shizuoka.ac.jp
N. Mase, S. Isomura, M. Toda, N. Watanabe, Synlett, 2013, 24, 2225-2228.
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Abstract
The use of hydrogen micro and nanobubbles (MNBs) enables an autoclave-free, gas-liquid-solid multiphase hydrogenation of carbon-carbon unsaturated bonds, in which a high concentration of hydrogen gas is maintained in the liquid phase.
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Key Words
gas-liquid-solid multiphase reactions, hydrogenation (alkenes, alkynes), micro and nanobubbles, heterogeneous catalysis, homogeneous catalysis, hydrogen
ID: J60-Y2013
