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Nickel-Catalyzed C-P Cross-Coupling of Arylboronic Acids with P(O)H Compounds

Gaobo Hu, Weizhu Chen, Tingting Fu, Zhimin Peng, Hongwei Qiao, Yuxing Gao* and Yufen Zhao

*Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China, Email: gaoxingchemxmu.edu.cn

G. Hu, W. Chen, T. Fu, Z. Peng, H. Qiao, Y. Gao, Y. Zhao, Org. Lett., 2013, 15, 5363-5365.

DOI: 10.1021/ol402672e



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Abstract

An efficient Ni-catalyzed coupling of a wide range of arylboronic acids with H-phosphites, H-phosphinate esters, and H-phosphine oxides provides various aryl-phosphorus compounds, including valuable triarylphosphine oxides, in very good yield.

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Key Words

phosphine oxides


ID: J54-Y2013