Cross-Hetero-Dehydrogenative Coupling Reaction of Phosphites: A Catalytic Metal-Free Phosphorylation of Amines and Alcohols
Jayaraman Dhineshkumar and Kandikere Ramaiah Prabhu*
*Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, Karnataka, India, Email: prabhuorgchem.iisc.ernet.in
J. Dhineshkumar, K. R. Prabhu, Org. Lett., 2013, 15, 6062-6065.
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Phosphorylation of amines, alcohols, and sulfoximines provides various phosphoramidates, phosphorus triesters and sulfoximine-derived phosphoramidates using molecular iodine as a catalyst and H2O2 as the sole oxidant under mild reaction conditions.
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phosphoramidates, phosphorus triesters, hydrogen peroxide, iodine