Phenyliodonium Diacetate Mediated Direct Synthesis of Benzonitriles from Styrenes through Oxidative Cleavage of C=C Bonds
Jin-Hui Xu, Qing Jiang and Can-Cheng Guo*
*College of Chemistry and Chemical Engineering, Hunan
University, Changsha 410082, China, Email: ccguo
hnu.edu.cn
J.-H. Xu, Q. Jiang, C.-C. Guo, J. Org. Chem., 2013, 78, 11881-11882.
DOI: 10.1021/jo401919h
see article for more reactions
Abstract
A metal-free PhI(OAc)2 mediated nitrogenation of alkenes via C=C bond cleavage using inorganic ammonia salt as nitrogen source under mild conditions affords nitriles in good yields. The method offers mild reaction conditions, operational simplicity, and use of an ammonium salt as nitrogen source. A plausible reaction mechanism is proposed.
see article for more examples
While ads financed 62% of the published abstracts in 2024, donations allowed us to publish additional 12%. 26% of the abstracts have been published voluntarly. If you kindly donate, we can publish more freely accessible information and help the chemical community even more:
If you don't like pawalls or a flood of more and more advertising, then you can send a clear signal here!
Key Words
ID: J42-Y2013
