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Silver-Catalyzed Vinylogous Fluorination of Vinyl Diazoacetates

Changming Qin and Huw M. L. Davies*

*Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322, United States, Email: hmdavieemory.edu

C. Qin, H. M. L. Davies, Org. Lett., 2013, 15, 6152-6154.

DOI: 10.1021/ol403017e (free Supporting Information)


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Abstract

A silver-catalyzed vinylogous fluorination of vinyl diazoacetates generates γ-fluoro-α,β-unsaturated carbonyls. Fluorination of farnesol and steroid derivatives was achieved.

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Key Words

fluorination


ID: J54-Y2013