Direct Cross-Coupling Access to Diverse Aromatic Sulfide: Palladium-Catalyzed Double C-S Bond Construction Using Na2S2O3 as a Sulfurating Reagent
Zongjun Qiao, Jianpeng Wei and Xuefeng Jiang*
*Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry, East China Normal University, 3663 North Zhonshan Road, Shanghai 200062, P. R. China, Email: xfjiangchem.ecnu.edu.cn
Z. Qiao, J. Wei, X. Jiang, Org. Lett., 2014, 16, 1212-1215.
DOI: 10.1021/ol500112y (free Supporting Information)
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The odorless and stable solid Na2S2O3·5H2O was used as a convenient and environmentally friendly source of sulfur in a Pd-catalyzed cross-coupling of aryl halides and alkyl halides to deliver aromatic sulfides.
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