Metal-Free Synthesis of N-Aryloxyimides and Aryloxyamines
Raju Ghosh and Berit Olofsson*
*Department of Organic Chemistry, Arrhenius Laboratory,
Stockholm University, SE-106 91 Stockholm, Sweden, Email:
berit
organ.su.se
R. Ghosh, B. Olofsson, Org. Lett., 2014, 16, 1830-1832.
DOI: 10.1021/ol500478t
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Abstract
N-Hydroxyphthalimide and N-hydroxysuccinimide have been arylated with diaryliodonium salts to provide N-aryloxyimides in excellent yields in short reaction times. A mild and hydrazine-free hydrolysis gives aryloxyamines, which are valuable building blocks in the synthesis of oxime ethers and benzofurans.
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Key Words
ID: J54-Y2014
