Regioselective N/C-Heterocyclization of Allenylindium Bromide Across Aryl Azides: One-Pot Synthesis of 5-Methyl-1,2,3-triazoles
Abid H. Banday*, Victor J. Hruby
*Department of Chemistry and Biochemistry, University of
Arizona, Tucson, AZ 85721, USA, Email: abidrrl
gmail.com
A. H. Banday, V. J. Hruby, Synlett, 2014, 25, 1859-1862.
Abstract
A regioselective one-pot synthesis of 1,5-disubstituted 1,2,3-triazoles through N/C-heterocyclization of allenylindium bromide across aryl azides is carried out under mild conditions in aqueous medium and proceeds in good yields.
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Key Words
heterocyclization, aryl azides, 1,2,3-triazoles, allenylindium bromide, regioselective reactions
ID: J60-Y2014
