Ligand-Controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2
Toni Moragas, Josep Cornella and Ruben Martin*
*Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain, Email: rmartinromoiciq.es
T. Moragas, J. Cornella, R. Martin, J. Am. Chem. Soc., 2014, 136, 17702-17705.
A Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO2 is mild, user-friendly, and operationally simple. The reaction is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.
see article for more examples
Ni-Catalyzed Direct Carboxylation of Benzyl Halides with CO2
T. León, A. Correa, R. Martin, J. Am. Chem. Soc., 2013, 135, 1221-1224.
Ni-Catalyzed Carboxylation of Unactivated Primary Alkyl Bromides and Sulfonates with CO2
Y. Liu, J. Cornella, R. Martin, J. Am. Chem. Soc., 2014, 136, 11212-11215.
carboxylation, allylation, Zn, Mn