Organic Chemistry Portal

Abstracts

Search:

Oxidative Coupling of Dichalcogenides with Sodium Sulfinates via Copper-Catalyzed Cleavage of S-S and Se-Se Bonds

Nobukazu Taniguchi*

*Department of Chemistry, Fukushima Medical University, Fukushima 960-1295, Japan, Email: tanigutifmu.ac.jp

N. Taniguchi, J. Org. Chem., 2015, 80, 1764-1765.

DOI: 10.1021/jo5026805



see article for more reactions

Abstract

A copper-catalyzed sulfonylation of disulfides using sodium sulfinates in air formed various sulfur-sulfone bonds efficiently and afforded thiosulfonates in good yields. Selenosulfonates could also be prepared.

see article for more examples



Key Words

thiosulfonates, oxygen


ID: J42-Y2015