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Use of Formate Salts as a Hydride and a CO2 Source in PGeP-Palladium Complex-Catalyzed Hydrocarboxylation of Allenes

Chuan Zhu, Jun Takaya and Nobuharu Iwasawa*

*Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Email: niwasawachem.titech.ac.jp

C. Zhu, J. Takaya, N. Iwasawa, Org. Lett., 2015, 17, 1814-1817.

DOI: 10.1021/acs.orglett.5b00692


Abstract

Formate salts can serve as hydride as well as a CO2 source in a mild PGeP-palladium complex-catalyzed hydrocarboxylation of allenes through a highly efficient decarboxylation-carboxylation process.


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Hydrocarboxylation of Allenes with CO2 Catalyzed by Silyl Pincer-Type Palladium Complex

J. Takaya, N. Iwasawa, J. Am. Chem. Soc., 2008, 130, 15254-15255.


Key Words

hydrocarboxylation, allylation


ID: J54-Y2015