Use of Formate Salts as a Hydride and a CO2 Source in PGeP-Palladium Complex-Catalyzed Hydrocarboxylation of Allenes
Chuan Zhu, Jun Takaya and Nobuharu Iwasawa*
*Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan, Email: niwasawachem.titech.ac.jp
C. Zhu, J. Takaya, N. Iwasawa, Org. Lett., 2015, 17, 1814-1817.
DOI: 10.1021/acs.orglett.5b00692
Abstract
Formate salts can serve as hydride as well as a CO2 source in a mild PGeP-palladium complex-catalyzed hydrocarboxylation of allenes through a highly efficient decarboxylation-carboxylation process.
see article for more examples
Hydrocarboxylation of Allenes with CO2 Catalyzed by Silyl Pincer-Type Palladium Complex
J. Takaya, N. Iwasawa, J. Am. Chem. Soc., 2008, 130, 15254-15255.
Key Words
hydrocarboxylation, allylation
ID: J54-Y2015