(Diacetoxyiodo)benzene-Mediated Reaction of Ethynylcarbinols: Entry to α,α′-Diacetoxy Ketones and Glycerol Derivatives
Qing-Rong Liu, Cheng-Xue Pan, Xiao-Pan Ma, Dong-Liang Mo* and Gui-Fa Su*
*Ministry of Education of China and School of Chemistry &
Pharmaceutical Sciences, Guangxi Normal University, 15 Yu Cai Road, Guilin
541004, China,
Email: moeastlight
mailbox.gxnu.edu.cn, gfysglgx163.com
Q.-R. Liu, C.-X. Pan, X.-P. Ma, D.-L. Mo, G.-F. Su, J. Org. Chem., 2015, 80, 6496-6501.
DOI: 10.1021/acs.joc.5b00740
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Abstract
The use of PhI(OAc)2 enables an efficient access to α,α′-diacetoxy ketones has from ethynylcarbinols. Glycerol derivatives can be easily synthesized in good yields via a one-pot reaction. A plausible mechanism is proposed.
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Key Words
ID: J42-Y2015
