Divergent Synthesis of 2-Aminofurans via Palladium-Catalyzed Acetoxylative, Alkoxylative, and Hydroxylative Cycloisomerization of Homoallenyl Amides
Cungui Cheng, Shuiyou Liu and Gangguo Zhu*
*Department of Chemistry, Zhejiang Normal University, 688
Yingbin Road, Jinhua 321004, China,
Email: gangguo
zjnu.cn
C. Cheng, S. Liu, G. Zhu, J. Org. Chem., 2015, 80, 7604-7612.
DOI: 10.1021/acs.joc.5b01182
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Abstract
Hypervalent iodine compounds enable Pd-catalyzed acetoxylative, alkoxylative, and hydroxylative cycloisomerizations of homoallenyl amides to give three different types of polysubstituted 2-aminofurans in promising yields at room temperature.
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Key Words
ID: J42-Y2015
