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Palladacycle-Catalyzed Carbonylative Suzuki-Miyaura Coupling with High Turnover Number and Turnover Frequency

Prashant Gautam and Bhalchandra M. Bhanage*

*Department of Chemistry, Institute of Chemical Technology, N.P. Marg, Matunga-400019, Mumbai, India, Email: bm.bhanageictmumbai.edu.in

P. Gautam, B. M. Bhanage, J. Org. Chem., 2015, 80, 7810-7815.

DOI: 10.1021/acs.joc.5b01160


Abstract

Palladacycles catalyze a carbonylative Suzuki-Miyaura coupling of aryl iodides with arylboronic acids with high turnover numbers and turnover frequencies. Comparison of the palladacycles with a conventional palladium source shows their superiority.

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Key Words

aryl ketones, Suzuki Coupling


ID: J42-Y2015